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Li ium aluminum hydride 16853-85-3 15 4. First-aid measures General Advice Show is safety data sheet to e dor in attendance. Immediate medical attention is required. Eye Contact Rinse immediately wi plenty of water, also under e eyelids, for at least 15 minutes. Small quantities of li ium aluminium hydride should be destroyed by quenching wi cold iso-propanol. Do not add any LiAlH4 to tissue paper. e following personal protective equipment (PPE) is to be used: Safety Glasses, Labcoat, Latex gloves, Long pants, Covered shoes If LiAlH4 dust is a problem, a surgical mask should be worn. Prepared by. LI IUM ALUMINUM HYDRIDE is a powerful reducing agent. React violently on contact wi many oxidizing agents. Ignites by friction, especially if powdered. Reacts vigorously wi hydroxy compounds such as water, alcohols, carboxylic acids [Mellor 2 Supp. 2:142. 1961]. Material Safety Data Sheet Li ium Aluminum Hydride, Tablets, 97 ACC 49880 Section 1 - Chemical Product and Company Identification: MSDS Name: Li ium Aluminum Hydride, Tablets, 97 Catalog Numbers: AC271270000, AC271270 0, AC271270250, AC27127 00. * Li ium aluminium hydride, LAH reagent cannot reduce an isolated non-polar multiple bond like C=C. However, e double or triple bonds in conjugation wi e polar multiple bonds can be reduced. * LiAlH 4 is a powerful reducing agent compared to sodium borohydride. Li ium tri-tert-butoxyaluminum hydride (LTBA) is a stable, mild reducing agent at is used to selectively reduce aldehydes and ketones in e presence of esters. It can also be used to reduce imidoyl chlorides to aldimines and aromatic disulfides to e corresponding iols. Packaging 5, 25, 0 g . Li ium aluminum hydride solution 2.0 M in F Synonym: LAH, Li ium alanate, Li ium tetrahydroaluminate CAS Number 16853-85-3. Linear Formula LiAlH 4. Molecular Weight 37.95. MDL number MFCD0001 75. PubChem Substance ID 24881465. NACRES NA.22. Material Safety Data Sheet Version 5.0 Revision Date 03/12/ Print Date 09/12/. PRODUCT AND COMPANY IDENTIFICATION Product name: Aluminium li ium hydride Product Number: 531502 Brand: Aldrich Supplier: Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63 3 USA Telephone: +1 800-325-5832 Fax: +1 800-325-5052. safety hazards of Li ium Aluminum Hydride to potentially exposed workers. LI IUM ALUMINUM HYDRIDE page 2 of 6 is Fact Sheet is a sum y source of information of all potential and most severe heal hazards at result from exposure. Duration of exposure, concentration of e. SAFETY OPERATING PROCEDURE TEMPLATE By signing and dating here e Principal Investigator/ or a designee certifies at e Safety Operating Procedure (SOP) for Li ium Aluminum Hydride is accurate and effectively provides guidance for employees and students in is lab. INLI009 - LI IUM ALUMINUM HYDRIDE, pellets LI IUM ALUMINUM HYDRIDE, pellets Safety Data Sheet INMG040 Date of issue: 07/23/ Version: 1.0 07/24/ EN (English US) SDS ID: INMG040 Page 1 SECTION 1: Identification of e substance/mixture and of e company/undertaking 1.1. Product identifier Product form: Substance. Communications Reduction of Acetals to E ers by Means of Li ium Aluminum Hydride-Aluminum Chloride. E. Eliel, M. Rerick, J. Org. Chem. 1958, 23, 88. Selective reductions. 28. e fast reaction of li ium aluminum hydride wi alkyl halides in tetrahydrofuran. A . Tetrahydrofuran. It should not be used to dry me yl e ers, or Tetrahydrofuran. Li ium Aluminum Hydride wi carbon dioxide in sodium bicarbonate at hight temperature is a fire hazard. When heated to omposition it emits irritating and toxic fumes of hydrogen gas, aluminum oxide, li ium hydroxide, aluminum, li ium hydride. Hafnium Hydride. Mixed wi oxidizing agents, HfH 2 is used as a constituent part in compositions for flares, fuzes, and combustion charges in pyrotechnics. HfH 2 will also be used as an alloying constituent in powder metallurgy. Li ium Hydride. Li ium forms ionic hydrides because of e strong electropositive character of e cation. SAFETY DATA SHEET Creation Date - - Revision Date 05- - Revision Number 5 SECTION 1: IDENTIFICATION OF E SUBSTANCE/MIXTURE AND OF E COMPANY/UNDERTAKING 1.1. Product identification Product Description: Li ium aluminium hydride, 2.4M solution in F. Page 1 of 7 LI IUM ALUMINIUM HYDRIDE CAS No 16853-85-3 MATERIAL SAFETY DATA SHEET SDS/MSDS SECTION 1: Identification of e substance/mixture and of e company/undertaking. • Li ium Aluminum Hydride reacts violently wi water and has a significant heat of solvation. erefore DO NOT add solvent to dry LiAlH 4. Instead, slowly add LiAlH 4 to anhydrous solvent in e reaction flask. e initial small amount of LiAlH 4 will react wi any trace amounts of water. Li ium Aluminum Hydride, typ. 15 solution in F / Toluene (typ. 3.5 M) Product Number: 401630 Date of Issue: /12/08 Page 3 / 3 e information presented herein is believed to be accurate and reliable, but is presented wi out guarantee or responsibility on e . SAFETY DATA SHEET Version 4. Revision Date 06/24/ Print Date 03/02/. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name: Li ium aluminum hydride Product Number: 199877 Brand: Aldrich Index-No.: 001-002-00-4 CAS-No.: 16853-85-3. Li ium aluminum hydride (0.66 mol) in 662 ml F was added dropwise to dibutyldie ylmalonate (0.55 mol) dissolved in 700 ml F while maintaining e temperature between –20 and 0 °C and e mixture stirred overnight at ambient temperature. e reaction was re-cooled to –20 °C and 40 ml water, 80 ml NaOH, and 80 ml of water were. As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meter (75 feet) for solids. Keep unau orized personnel away. Stay upwind. Keep out of low areas. Ventilate e area before entry. /Li ium aluminum hydride. Li ium aluminum hydride, e ereal/. Product Name: Li ium aluminium hydride (CAS NO.16853-85-3) Molecular Formula: LiAlH 4 Molecular Weight: 37.95g/mol Mol File: 16853-85-3.mol EINECS: 240-877-9. ALUMINUM HYDRIDE is a powerful reducing agent. react violently wi oxidizers. Prolonged exposure to heat cause spontaneous omposition. Can also ompose spontaneously at ambient temperature wi explosive violence. Occasionally, explosions have occurred when it . 16,  · is video provides an overview of e reactions of carboxylic acid derivatives wi li ium aluminum hydride or Grignard reagents. It is an . Li ium Aluminum Hydride is generally immediately available in most volumes. American Elements offers a broad range of products for hydrogen storage research, advanced fuel cells and battery applications. Hydrogen can easily be generated from renewable energy sources and is e most abundant element in e universe. Shop a large selection of products and learn more about Li ium Aluminium Hydride, 2.4M Solution in F, AcroSeal, ACROS Organics. 0mL. AcroSeal glass bottle packed. Mono- and Bimetallic Aluminum Alkyl, Alkoxide, Halide and Hydride Complexes of a Bulky Conjugated Bis-Guanidinate(CBG) Ligand and Aluminum Alkyls as Precatalysts for Carbonyl Hydroboration. Li ium and strontium isotope dynamics in a carbonate island aquifer, Rottnest Island, Western Australia. Approx. Rs 0 / Unit Get Latest Price Owing to perfection and quality oriented approach, we have carved niche in e industry by offering Li ium Aluminium Hydride. e offered li ium aluminum hydride is processed by experts utilizing best quality chemical compounds and advanced me odology keeping in mind e standards of industry. Alison Frontier, University of Rochester. Supported by a grant from e National Science Foundation. NSF Funding {+} is material is based upon work supported by e National Science Foundation under Grant Number CHE-1565813. Any opinions, findings, and conclusions or recommendations expressed in is material are ose of e au or(s) and do not necessarily reflect . We would like to report a potential hazard for e syn etic procedure outlined in Physical Review B (1999, 60, 2704). is contribution is widely referenced and describes a procedure for preparing hydride surface-terminated silicon nanoparticles via li ium aluminum hydride reduction of SiCl4 in micellular tetrahydrofuran solutions. e au ors incorrectly report at is reaction produces. Li ium Aluminium Hydride (LAH or [ma ]LiAlH_4[/ma ]) is a strong reducing agent. It can reduce almost all functional groups except alkenes, alkynes, benzene and e ers. In addition to is, [ma ]3[/ma ] and [ma ]4[/ma ] membered cyclic e e. Chemical hydride storage is an alternative me od of producing hydrogen via a chemical reaction. ese reactions involve chemical hydrides, water, and alcohols. e chemical reactions are not reversible, and e byproducts must be discarded. OSHA Vacated PELs: Li ium aluminum deuteride: No OSHA Vacated PELs are listed for is chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations . A researcher who was experienced at disposing of materials, ided to dispose of a very old container of li ium aluminum hydride(LAH) which was not being used due to it's questionable quality. e researcher ought at e material needed to be stabilized before packaging. Similar in reactivity to li ium aluminum hydride. react violently wi oxidizing agents. An explosion occurred during its preparation from sodium and aluminum in a medium of tetrahydrofuran [Chem. Eng. News 39(40):57 1961]. At elevated temperatures, e hydride reduces carbon dioxide or sodium hydrogen carbonate to me ane and e ane. 16853-85-3 Li ium aluminum hydride 2 Exhibit 1 7439-93-2 Li Wire 1 Exhibit 1 16940-66-2 sodium borohydride 2 Exhibit 1 7439-93-2 Li ium 1 Exhibit 1 7440-23-5 Sodium 1 Exhibit 1 7440-23-5 sodium in kerosene 1 Exhibit 1 . ANSI Z87.1-compliant safety glasses wi . metal hydrides (sodium hydride, germane, li ium aluminum hydride) alkyl metal hydrides (butylli ium, trime ylaluminum, trie ylboron) metal carbonyls (nickel carbonyl, iron pentacarbonyl) gases (arsine, diborane, phosphine, silane) Evacuate e lab and contact Public Safety (911 from a campus or 609-258-7882 from a cell phone. Li ium Aluminum Hydride found in: Li ium aluminum hydride, 95 min, Li ium aluminum hydride, =97.0 (gas-volumetric), Li ium aluminum hydride. Alibaba.com offers 185 li ium aluminium hydride lah products. About 62 of ese are pharmaceutical intermediates, 15 are syn eses material intermediates, and 12 are o er organic intermediates. A wide variety of li ium aluminium hydride lah options are available to you, such as flavor & fragrance intermediates, pharmaceutical intermediates, and agrochemical intermediates. For example, it was used to syn esis sodium aluminum hydride and li ium aluminum hydride from NaH and Al powder and LiH and Al powder, respectively. e unique feature of is route is at it enables e syn esis of ese complex hydride materials at room temperature and at relatively low hydrogen pressures. Stanley Howell Program Manager - Chemical Safety 609-258-2711. Steve Elwood Associate Director for Laboratory Safety 609-258-6271. Li ium hydride is used in e production of a wide variety of reagents, such as, li ium boro-hydride and li ium aluminum hydride, for organic syn esis. Li ium Hydride ket: Regional Outlook In terms of region, e global li ium hydride ket can be segmented into Asia Pacific, Europe, Latin America, Nor America, and Middle East & Africa.

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